Methyl Anthranilate

Aroma chemical · Floral / Fruity

orange blossom, grape, sweet, floral — heart note.

Aroma illustration for Methyl Anthranilate: white orange blossoms and a bunch of grapes, for its orange blossom and grape notes. It illustrates smell associations, not the material or its source.Skeletal formula of Methyl Anthranilate, C8H9NO2, drawn from PubChem's 2D record. Stereochemistry is not shown.
Aroma View: an illustration of what Methyl Anthranilate smells like (orange blossom, grape), drawn by RUŌOD Lab — not its appearance or its source.Skeletal formula drawn by RUŌOD Lab from PubChem's 2D record (CID 8635). Stereochemistry is not shown; the coloured background is decoration.
Images

By the RUŌOD Lab TeamRevision 1Updated

In short

Methyl anthranilate is an ester found in orange blossom, neroli, jasmine and Concord grapes. It gives the grape-like, orange-blossom sweetness of white flowers.

What Methyl Anthranilate smells like

Methyl anthranilate has an orange-blossom odour and a sweet, fruity Concord-grape character; its taste is sweet, fruity and grape-like with a musty, berry nuance. A glossary likens it to Concord grape juice crossed with neroli. It reacts readily with aldehydes to form Schiff bases — aurantiol, made with hydroxycitronellal, is the best known — and it discolours soap and cosmetics, which limits its use there.

Leading note
Orange blossom
Clear facets
Concord grape
Supporting facets
Musty
Faint facets
Berry
Character
Sweet, fruity, heavy, floral
  • orange blossom
  • grape
  • sweet
  • floral

What makes Methyl Anthranilate distinctive

Grape. It is the orange-blossom material that also smells of grape juice — the note behind grape flavour as much as behind orange flower.

How Methyl Anthranilate is used

Used in orange-blossom, neroli and white-floral compositions, and in grape flavours; it is the starting point for Schiff bases. It discolours in soap and with aldehydes.

Typical role: modifier (used in small amounts to change the character of a blend).

How Methyl Anthranilate differs from similar materials

Dimethyl Anthranilate
Dimethyl anthranilate is softer and more mandarin-citrus, and does not discolour with aldehydes; methyl anthranilate is grape and orange blossom.
Aurantiol
Aurantiol is methyl anthranilate combined with hydroxycitronellal — sweeter, deeper, more balsamic and far longer-lasting.

Each difference compares the published descriptions of the two materials. Smell varies with grade, supplier and dilution; compare them side by side on blotters before substituting one for another.

Formulation considerations

Reacts with aldehydes, causing yellowing or browning; plan for discoloration in formulas containing both.

Identity and classification

Type
Aroma chemical
Origin
Occurs in nature
Odour family
Floral / Fruity
Note position
Heart note
Physical form at room temperature
Liquid
CAS number
134-20-3
Molecular formula
C8H9NO2
Molecular weight
151.16 g/mol
IUPAC name
methyl 2-aminobenzoate

The CAS number, formula and molecular weight are taken from PubChem compound 8635, whose own record lists this CAS number; checked 19 October 2026.

Safety and compliance

Hazard classification of the neat substance, as PubChem summarises it, read 26 October 2026. Companies notifying the ECHA C&L Inventory classify it (2,660 reports): H319 causes serious eye irritation (99.8% of reports). 4 of the reports find it does not meet the hazard criteria. Unless it is harmonised, this is the notifiers' own classification, not a binding one.

This page is general information, not a safety assessment or a specification. Confirm identity, composition, IFRA status and allergen content from your supplier's documents for the lot you hold.

Materials it works with

Methyl Anthranilate is also suggested as a partner on the pages for Aurantiol, Champaca Absolute, Jasmine Sambac Absolute, Methyl beta-Naphthyl Ketone and Yara Yara.

Used in formulas and accords

Used in 24 published formulas

Methyl Anthranilate is an ingredient in 12 perfume formulas, 9 accords and 3 bases in the Formula & Accord Library.

Community formulas

RUŌOD House Originals

Original compositions by RUŌOD House.

Further reading

Questions about Methyl Anthranilate

Is Methyl Anthranilate natural or synthetic?

The molecule occurs in nature. Commercial Methyl Anthranilate may be made by synthesis or obtained from natural sources, so check the supplier's specification if the distinction matters to you.

What is the CAS number of Methyl Anthranilate?

134-20-3. It was checked against PubChem on 19 October 2026.

Which published formulas use Methyl Anthranilate?

Methyl Anthranilate is used in 24 published formulas in the RUŌOD Lab Formula & Accord Library, including Açaí Accord, Black Musk and Brine Blossom Accord. Each is listed with a link under "Used in formulas and accords" on this page.

Sources

Your own records, next to the reference

Keep your own record of Methyl Anthranilate — supplier, cost, stock, dilutions and where it is used — in RUŌOD Lab's material library.