1-Octen-3-ol

Aroma chemical · Green / Aromatic

mushroom, earthy, green, herbal — top to heart note.

Aroma illustration for 1-Octen-3-ol: mushrooms, green leaves and a sprig of herbs, for its mushroom, green and herbal notes. It illustrates smell associations, not the material or its source.Skeletal formula of 1-Octen-3-ol (Mushroom alcohol), C8H16O, drawn from PubChem's 2D record. Stereochemistry is not shown.
Aroma View: an illustration of what 1-Octen-3-ol smells like (mushroom, green, herbal), drawn by RUŌOD Lab — not its appearance or its source.Skeletal formula drawn by RUŌOD Lab from PubChem's 2D record (CID 18827). Stereochemistry is not shown; the coloured background is decoration.
Images

By the RUŌOD Lab TeamRevision 1Updated

In short

1-Octen-3-ol, called mushroom alcohol, is the compound most responsible for the smell of fresh mushrooms. It also occurs in lavender and some mints and is used in traces.

What 1-Octen-3-ol smells like

Oct-1-en-3-ol, mushroom alcohol, smells unmistakably of raw mushroom and earth. Sigma-Aldrich lists green, mushroom, oily and earthy, and notes it is the most prominent odour volatile produced by many fungi. Perfumery descriptions add metallic and slightly fatty undertones. It is extremely potent — detectable at around a part per billion in air — and the natural form found in edible mushrooms is reported to be the more characteristically mushroom-like of its two mirror-image forms.

Leading note
Raw mushroom
Clear facets
Earthy
Supporting facets
Green, metallic
Faint facets
Oily
Character
Earthy, damp, raw, potent
  • mushroom
  • earthy
  • green
  • herbal

What makes 1-Octen-3-ol distinctive

It is the mushroom itself — the defining volatile of fungi — rather than a green note that suggests earth.

Concentration and dilution

Extremely potent; it is used in traces, from a dilution.

How 1-Octen-3-ol is used

Used in traces to give realism to green, forest-floor, damp-soil and mushroom accords, and in mushroom flavours.

Typical role: modifier (used in small amounts to change the character of a blend).

How 1-Octen-3-ol differs from similar materials

cis-3-Hexenyl Tiglate
The tiglate is a green, floral-fruity ester with a hint of fresh mushroom; oct-1-en-3-ol is raw mushroom and earth outright.
1-Octen-3-one
1-Octen-3-one is the ketone: more intense and markedly metallic; the alcohol is the rounder mushroom.

Each difference compares the published descriptions of the two materials. Smell varies with grade, supplier and dilution; compare them side by side on blotters before substituting one for another.

Formulation considerations

Extremely diffusive; overdosing gives an unpleasant damp note. Work from a 0.1% dilution.

Identity and classification

Type
Aroma chemical
Origin
Occurs in nature
Odour family
Green / Aromatic
Note position
Top to heart note
Physical form at room temperature
Liquid
Also known as
Mushroom alcohol, Oct-1-en-3-ol, Matsutakeol
CAS number
3391-86-4
Molecular formula
C8H16O
Molecular weight
128.21 g/mol
IUPAC name
oct-1-en-3-ol

The CAS number, formula and molecular weight are taken from PubChem compound 18827, whose own record lists this CAS number; checked 19 October 2026.

Safety and compliance

Hazard classification of the neat substance, as PubChem summarises it, read 26 October 2026. Companies notifying the ECHA C&L Inventory classify it (1,788 reports): H315 causes skin irritation (99.9% of reports); H319 causes serious eye irritation (99.8% of reports); H332 harmful if inhaled (97.4% of reports); H302 harmful if swallowed (96.6% of reports); H400 very toxic to aquatic life (93.9% of reports). Unless it is harmonised, this is the notifiers' own classification, not a binding one.

This page is general information, not a safety assessment or a specification. Confirm identity, composition, IFRA status and allergen content from your supplier's documents for the lot you hold.

Materials it works with

1-Octen-3-ol is also suggested as a partner on the pages for Geosmin.

Used in formulas and accords

Used in 20 published formulas

1-Octen-3-ol is an ingredient in 14 perfume formulas and 6 accords in the Formula & Accord Library.

Community formulas

RUŌOD House Originals

Original compositions by RUŌOD House.

Further reading

Questions about 1-Octen-3-ol

Is 1-Octen-3-ol natural or synthetic?

The molecule occurs in nature. Commercial 1-Octen-3-ol may be made by synthesis or obtained from natural sources, so check the supplier's specification if the distinction matters to you.

What is the CAS number of 1-Octen-3-ol?

3391-86-4. It was checked against PubChem on 19 October 2026.

Which published formulas use 1-Octen-3-ol?

1-Octen-3-ol is used in 20 published formulas in the RUŌOD Lab Formula & Accord Library, including Asphalt Peony, Blood Accord and Bright Wolf. Each is listed with a link under "Used in formulas and accords" on this page.

Sources

Your own records, next to the reference

Keep your own record of 1-Octen-3-ol — supplier, cost, stock, dilutions and where it is used — in RUŌOD Lab's material library.