cis-3-Hexenyl Tiglate

Aroma chemical · Green / Floral

green, earthy, herbal, floral — heart note.

Aroma illustration for cis-3-Hexenyl Tiglate: green leaves, a mound of dark earth and a sprig of herbs, for its green, earthy and herbal notes. It illustrates smell associations, not the material or its source.Skeletal formula of cis-3-Hexenyl Tiglate ((Z)-Hex-3-enyl (E)-2-methylbut-2-enoate), C11H18O2, drawn from PubChem's 2D record. Stereochemistry is not shown.
Aroma View: an illustration of what cis-3-Hexenyl Tiglate smells like (green, earthy, herbal), drawn by RUŌOD Lab — not its appearance or its source.Skeletal formula drawn by RUŌOD Lab from PubChem's 2D record (CID 15461361). Stereochemistry is not shown; the coloured background is decoration.
Images

By the RUŌOD Lab TeamRevision 1Updated

In short

cis-3-Hexenyl tiglate is an ester of leaf alcohol and tiglic acid with a warm green, earthy odour. It adds a natural, stem-like greenness to white florals.

What cis-3-Hexenyl Tiglate smells like

Cis-3-hexenyl tiglate is a green ester with an earthy warmth. Bedoukian describes the odour as fresh, green, floral and fruity with hints of chamomile, and the taste as earthy and mushroom-like; other suppliers describe it as green-earthy with a fresh-cut mushroom quality, floral gardenia and fruity banana. The Good Scents Company lists green, earthy and vegetative with mushroom and radish nuances. The common thread is green made warm and earthy rather than sharp.

Leading note
Warm, earthy green
Clear facets
Fresh mushroom
Supporting facets
Herbal, chamomile-like floral
Faint facets
Banana, radish
Character
Green, earthy, warm, soft
  • green
  • earthy
  • herbal
  • floral

What makes cis-3-Hexenyl Tiglate distinctive

Its earthiness. A supplier contrasts it with cis-3-hexenyl acetate: the simple esters give straightforward fresh green, while the tiglate adds warmth and complexity — a fresh mushroom and herb quality, not mouldy, that sets it apart from the fruity leaf esters.

How cis-3-Hexenyl Tiglate is used

Used for natural, herbal green effects; one supplier notes it works well with leafy herbal and fougère types. In flavours it is suggested for mushroom, lemon and lime.

Typical role: modifier (used in small amounts to change the character of a blend).

How cis-3-Hexenyl Tiglate differs from similar materials

cis-3-Hexenyl Acetate
A supplier contrasts them directly: the acetate is the straightforward fresh green, the tiglate warmer, earthier and more complex. (compared directly by a cited source)
1-Octen-3-ol
Mushroom alcohol is raw mushroom and earth itself; the tiglate only hints at fresh mushroom inside a green, floral-fruity ester.

An asterisk marks a difference that a cited source states directly. The others compare the published descriptions of each material. Smell varies with grade, supplier and dilution; compare them side by side on blotters before substituting one for another.

Identity and classification

Type
Aroma chemical
Origin
Occurs in nature
Odour family
Green / Floral
Note position
Heart note
Physical form at room temperature
Liquid
Also known as
(Z)-Hex-3-enyl (E)-2-methylbut-2-enoate
CAS number
67883-79-8
Molecular formula
C11H18O2
Molecular weight
182.26 g/mol
IUPAC name
[(Z)-hex-3-enyl] (E)-2-methylbut-2-enoate

The CAS number, formula and molecular weight are taken from PubChem compound 15461361, whose own record lists this CAS number; checked 19 October 2026.

Safety and compliance

Hazard classification of the neat substance, as PubChem summarises it, read 26 October 2026. Companies notifying the ECHA C&L Inventory classify it (171 reports): H315 causes skin irritation (25.7% of reports). 126 of the reports find it does not meet the hazard criteria. Unless it is harmonised, this is the notifiers' own classification, not a binding one.

This page is general information, not a safety assessment or a specification. Confirm identity, composition, IFRA status and allergen content from your supplier's documents for the lot you hold.

Materials it works with

Used in formulas and accords

Used in 3 published formulas

cis-3-Hexenyl Tiglate is an ingredient in 3 perfume formulas in the Formula & Accord Library.

RUŌOD House Originals

Original compositions by RUŌOD House.

Further reading

Questions about cis-3-Hexenyl Tiglate

Is cis-3-Hexenyl Tiglate natural or synthetic?

The molecule occurs in nature. Commercial cis-3-Hexenyl Tiglate may be made by synthesis or obtained from natural sources, so check the supplier's specification if the distinction matters to you.

What is the CAS number of cis-3-Hexenyl Tiglate?

67883-79-8. It was checked against PubChem on 19 October 2026.

Which published formulas use cis-3-Hexenyl Tiglate?

cis-3-Hexenyl Tiglate is used in 3 published formulas in the RUŌOD Lab Formula & Accord Library: Bracken Moon, Gardenia Milk and Green Pod Theory. Each is listed with a link under "Used in formulas and accords" on this page.

Sources

Your own records, next to the reference

Keep your own record of cis-3-Hexenyl Tiglate — supplier, cost, stock, dilutions and where it is used — in RUŌOD Lab's material library.