Ethyl 2-Methylbutyrate

Aroma chemical · Fruity / Green

apple, fruity, juicy, green — top note.

Aroma View image for Ethyl 2-Methylbutyrate, illustrating its apple and green notes. It shows smell associations, not the material or its source.Skeletal formula of Ethyl 2-Methylbutyrate, C7H14O2, drawn from PubChem's 2D record. Stereochemistry is not shown.
Aroma View: an approved image of what Ethyl 2-Methylbutyrate smells like — not its appearance or its source.Skeletal formula drawn by RUŌOD Lab from PubChem's 2D record (CID 24020). Stereochemistry is not shown; the coloured background is decoration.
Images

By the RUŌOD Lab TeamRevision 1Updated

In short

Ethyl 2-methylbutyrate is a fruity ester found in apples and many other fruits. It gives a fresh, juicy green-apple note to the top of a fragrance.

What Ethyl 2-Methylbutyrate smells like

Ethyl 2-methylbutyrate is a powerful, green-fruity, apple-like ester. Givaudan describes fruity and green with apple-peel and pineapple-skin notes and a very diffusive fruity effect; Symrise estery and very fruity, reminiscent of papaya, apple, quince, apricot and strawberry; PerfumersWorld green-fruity, apple peel, plum and ethereal. It occurs naturally in apples, strawberries and pineapple, and its odour threshold is extremely low.

Leading note
Fresh apple
Clear facets
Apple peel, green
Supporting facets
Pineapple skin
Faint facets
Berry, strawberry, ethereal
Character
Juicy, fresh, diffusive, green
  • apple
  • fruity
  • juicy
  • green

What makes Ethyl 2-Methylbutyrate distinctive

The apple peel: crisp, green and juicy at once, and very diffusive — the most literal fresh-apple ester.

How Ethyl 2-Methylbutyrate is used

Used as a diffusive fruity modifier in floral accords and with other fruity esters, and in apple, strawberry and pineapple flavours.

Typical role: modifier (used in small amounts to change the character of a blend); lift (adds diffusion and radiance, especially at the top).

How Ethyl 2-Methylbutyrate differs from similar materials

Manzanate
Manzanate adds pineapple and a cider character; ethyl 2-methylbutyrate is the greener, more literal apple peel.
Fructone
Fructone is a sweeter, longer-lasting apple with pineapple, strawberry and a woody note; ethyl 2-methylbutyrate is fresher, greener and more diffusive.
Hexyl 2-Methylbutyrate
The hexyl ester is waxier and greener, with unripe strawberry and banana; the ethyl ester is brighter, juicier apple.
Verdox
Verdox is a woody, Granny-Smith apple that turns synthetic and sharp when overdosed; ethyl 2-methylbutyrate is a juicier, more natural apple peel.
Isopropyl 2-Methylbutyrate
Isopropyl 2-methylbutyrate, the isopropyl ester of the same acid, is greener and more tropical, with pineapple and pear.

Each difference compares the published descriptions of the two materials. Smell varies with grade, supplier and dilution; compare them side by side on blotters before substituting one for another.

Formulation considerations

Very volatile; it fades quickly.

Identity and classification

Type
Aroma chemical
Origin
Occurs in nature
Odour family
Fruity / Green
Note position
Top note
Physical form at room temperature
Liquid
CAS number
7452-79-1
Molecular formula
C7H14O2
Molecular weight
130.18 g/mol
IUPAC name
ethyl 2-methylbutanoate

The CAS number, formula and molecular weight are taken from PubChem compound 24020, whose own record lists this CAS number; checked 19 October 2026.

Safety and compliance

Hazard classification of the neat substance, as PubChem summarises it, read 26 October 2026. Companies notifying the ECHA C&L Inventory report it as not meeting the GHS hazard criteria (0 of 1,873 reports). Unless it is harmonised, this is the notifiers' own classification, not a binding one.

This page is general information, not a safety assessment or a specification. Confirm identity, composition, IFRA status and allergen content from your supplier's documents for the lot you hold.

Materials it works with

Ethyl 2-Methylbutyrate is also suggested as a partner on the pages for Amyl Acetate, Cerezoate, Fraistone, Fruitaleur, Fruitate and Isobutyl Isovalerate.

Used in formulas and accords

Used in 7 published formulas

Ethyl 2-Methylbutyrate is an ingredient in 1 perfume formula, 5 accords and 1 base in the Formula & Accord Library.

Community formulas

RUŌOD House Originals

Original compositions by RUŌOD House.

Further reading

Questions about Ethyl 2-Methylbutyrate

Is Ethyl 2-Methylbutyrate natural or synthetic?

The molecule occurs in nature. Commercial Ethyl 2-Methylbutyrate may be made by synthesis or obtained from natural sources, so check the supplier's specification if the distinction matters to you.

What is the CAS number of Ethyl 2-Methylbutyrate?

7452-79-1. It was checked against PubChem on 19 October 2026.

Which published formulas use Ethyl 2-Methylbutyrate?

Ethyl 2-Methylbutyrate is used in 7 published formulas in the RUŌOD Lab Formula & Accord Library, including Blueberry Accord, Cherry Accord and Dragon Fruit Accord. Each is listed with a link under "Used in formulas and accords" on this page.

Sources

Your own records, next to the reference

Keep your own record of Ethyl 2-Methylbutyrate — supplier, cost, stock, dilutions and where it is used — in RUŌOD Lab's material library.