In short
Diethyl phthalate (DEP) is a nearly odourless ester long used as a solvent and fixative-diluent in fragrance oils. Many brands now avoid it and use DPG, IPM or triethyl citrate instead.
What Diethyl Phthalate (DEP) smells like
Diethyl phthalate (DEP) is a clear, colourless, oily liquid that supplier specifications describe as nearly or practically odourless, or with very little odour; one distributor mentions a slight aromatic odour. It has long been used as a solvent and fixative that dilutes perfume oils and slows the evaporation of volatile notes. Concerns about phthalates have led many to replace it with triethyl citrate.
- Leading note
- No single note leads in the published descriptions
- Faint facets
- Slight aromatic
- Character
- Neutral, oily, low-volatility
What makes Diethyl Phthalate (DEP) distinctive
The older oily diluent of perfume oils, now often replaced by triethyl citrate over concerns about phthalates.
How Diethyl Phthalate (DEP) is used
Used as a solvent and fixative for perfume oils; triethyl citrate is often used in its place.
Typical role: solvent (dilutes or carries other materials).
How Diethyl Phthalate (DEP) differs from similar materials
- Triethyl Citrate
- Triethyl citrate is positioned as DEP's replacement, nearly odourless with a faint fruity, wine-like nuance when smelled neat. (compared directly by a cited source)
- Benzyl Benzoate
- Benzyl benzoate is also a solvent and fixative but has a faint sweet, balsamic, almond-like odour of its own.
An asterisk marks a difference that a cited source states directly. The others compare the published descriptions of each material. Smell varies with grade, supplier and dilution; compare them side by side on blotters before substituting one for another.
Formulation considerations
Some retailers and brands exclude phthalates as a policy; check your market and your customers' requirements before using it.
Identity and classification
- Type
- Solvent or carrier
- Origin
- Synthetic
- Odour family
- No odour family
- Note position
- Base note
- Physical form at room temperature
- Liquid
- Also known as
- Ethyl phthalate, DEP
- CAS number
- 84-66-2
- Molecular formula
- C12H14O4
- Molecular weight
- 222.24 g/mol
- IUPAC name
- diethyl benzene-1,2-dicarboxylate
The CAS number, formula and molecular weight are taken from PubChem compound 6781, whose own record lists this CAS number; checked 19 October 2026.
Safety and compliance
Hazard classification of the neat substance, as PubChem summarises it, read 26 October 2026. Companies notifying the ECHA C&L Inventory report it as not meeting the GHS hazard criteria (1,710 of 1,769 reports). Unless it is harmonised, this is the notifiers' own classification, not a binding one.
This page is general information, not a safety assessment or a specification. Confirm identity, composition, IFRA status and allergen content from your supplier's documents for the lot you hold.
Materials it works with
Used in formulas and accords
Used in 2 published formulas
Diethyl Phthalate (DEP) is an ingredient in 2 perfume formulas in the Formula & Accord Library.
Further reading
Questions about Diethyl Phthalate (DEP)
Is Diethyl Phthalate (DEP) natural or synthetic?
Diethyl Phthalate (DEP) is synthetic — it is made by chemical synthesis.
What is the CAS number of Diethyl Phthalate (DEP)?
84-66-2. It was checked against PubChem on 19 October 2026.
Which published formulas use Diethyl Phthalate (DEP)?
Diethyl Phthalate (DEP) is used in 2 published formulas in the RUŌOD Lab Formula & Accord Library: Black Musk and Hindi Maliki Qadeem. Each is listed with a link under "Used in formulas and accords" on this page.
Sources
- PubChem — compound 6781, checked 19 October 2026.
- PubChem — GHS classification (the ECHA C&L Inventory notifications and any harmonised EU entry), read 26 October 2026.
- Univar Solutions — Diethyl phthalate (fragrance grade) — distributor's description.
- MySkinRecipes — Diethyl phthalate — distributor's description.
- Scent.vn — Triethyl citrate (on replacing DEP) — distributor's description.
- Olfactory profile: the RUŌOD Lab team's synthesis of the published descriptions above, reviewed 21 October 2026. Evidence: more than one published description. Classification and the short description: revision 1. Descriptions of odour are judgement, not measurement.








