Acetophenone

Aroma chemical · Floral / Fruity

sweet, almond, hawthorn, pungent — top to heart note.

Aroma illustration for Acetophenone: almonds and white hawthorn blossoms, for its almond and hawthorn notes. It illustrates smell associations, not the material or its source.Skeletal formula of Acetophenone (1-Phenylethanone), C8H8O, drawn from PubChem's 2D record. Stereochemistry is not shown.
Aroma View: an illustration of what Acetophenone smells like (almond, hawthorn), drawn by RUŌOD Lab — not its appearance or its source.Skeletal formula drawn by RUŌOD Lab from PubChem's 2D record (CID 7410). Stereochemistry is not shown; the coloured background is decoration.
Images

By the RUŌOD Lab TeamRevision 1Updated

In short

Acetophenone is the simplest aromatic ketone. It has a sweet, pungent odour of hawthorn and bitter almond and occurs in many flowers, fruits and castoreum.

What Acetophenone smells like

Acetophenone is sweet, penetrating and floral, with almond and hawthorn at its core. The Good Scents Company lists sweet, pungent, hawthorn, mimosa, almond and acacia; other references add balsamic, narcissus, cherry pit and hints of orange blossom or jasmine. At full strength a perfume supplier finds a leathery, nutty almond character, while dilution brings out heliotrope, vanilla and blossom tones such as hawthorn and acacia.

Leading note
Sweet almond-hawthorn
Clear facets
Mimosa, acacia
Supporting facets
Orange blossom, balsamic
Faint facets
Leathery
Character
Sweet, pungent, sharp, floral
  • sweet
  • almond
  • hawthorn
  • pungent

What makes Acetophenone distinctive

Its pungency. It is the harsher, more penetrating hawthorn material — almond and leather in concentration, mimosa and blossom in dilution.

Concentration and dilution

Harsh, leathery and nutty neat; on dilution it turns to heliotrope, vanilla and blossom notes such as hawthorn and acacia.

How Acetophenone is used

Used in traces in hawthorn, mimosa, orange-blossom and heliotrope compositions, usually from a dilution.

Typical role: modifier (used in small amounts to change the character of a blend).

How Acetophenone differs from similar materials

4-Methylacetophenone
Methyl acetophenone is described as milder than acetophenone, with a fruity, cherry-like sweetness; acetophenone is sharper and more pungent. (compared directly by a cited source)
Anisaldehyde
Anisaldehyde is sweeter and more powdery-floral; acetophenone is sharper, more pungent and almond-like.

An asterisk marks a difference that a cited source states directly. The others compare the published descriptions of each material. Smell varies with grade, supplier and dilution; compare them side by side on blotters before substituting one for another.

Formulation considerations

Freezes at around room temperature, so it may need warming before weighing.

Identity and classification

Type
Aroma chemical
Origin
Occurs in nature
Odour family
Floral / Fruity
Note position
Top to heart note
Physical form at room temperature
Liquid. Freezes at about 20 °C, so it may be crystalline in a cool room (melting point 19–20 °C in PubChem's records).
Also known as
1-Phenylethanone, Methyl phenyl ketone
CAS number
98-86-2
Molecular formula
C8H8O
Molecular weight
120.15 g/mol
IUPAC name
1-phenylethanone

The CAS number, formula and molecular weight are taken from PubChem compound 7410, whose own record lists this CAS number; checked 19 October 2026.

Safety and compliance

Hazard classification of the neat substance, as PubChem summarises it, read 26 October 2026. It has a harmonised EU classification (Regulation (EC) No 1272/2008, Annex VI): H302 harmful if swallowed; H319 causes serious eye irritation. Companies notifying the ECHA C&L Inventory classify it (2,981 reports): H319 causes serious eye irritation (99.9% of reports). 2 of the reports find it does not meet the hazard criteria. Unless it is harmonised, this is the notifiers' own classification, not a binding one.

This page is general information, not a safety assessment or a specification. Confirm identity, composition, IFRA status and allergen content from your supplier's documents for the lot you hold.

Materials it works with

Acetophenone is also suggested as a partner on the pages for Methyl Anisate.

Used in formulas and accords

Used in 1 published formula

Acetophenone is an ingredient in 1 accord in the Formula & Accord Library.

Further reading

Questions about Acetophenone

Is Acetophenone natural or synthetic?

The molecule occurs in nature. Commercial Acetophenone may be made by synthesis or obtained from natural sources, so check the supplier's specification if the distinction matters to you.

What is the CAS number of Acetophenone?

98-86-2. It was checked against PubChem on 19 October 2026.

Which published formulas use Acetophenone?

Acetophenone is used in 1 published formula in the RUŌOD Lab Formula & Accord Library: Cherry Accord. Each is listed with a link under "Used in formulas and accords" on this page.

Sources

Your own records, next to the reference

Keep your own record of Acetophenone — supplier, cost, stock, dilutions and where it is used — in RUŌOD Lab's material library.