In short
Hexyl butyrate is a fruity ester with a fresh green-apple odour. It occurs in apples and other fruit and is used for crisp, natural apple effects.
What Hexyl Butyrate smells like
Hexyl butyrate is a green, fruity ester with an apple character and a waxy, slightly soapy skin. Supplier data list green, sweet, fruity, apple, waxy and soapy; a perfumery entry green, fruity, estery and vegetative with a waxy undertone; Blue Marble's natural grade green, fruity, sweet, soapy and waxy, apple-like. Its taste is green, fruity, waxy and soapy.
- Leading note
- Green apple
- Clear facets
- Waxy skin
- Supporting facets
- Soapy
- Faint facets
- Vegetative
- Character
- Green, waxy, fresh
What makes Hexyl Butyrate distinctive
Apple skin rather than apple flesh: green and waxy, with a faint soapiness.
How Hexyl Butyrate is used
Used in green-apple and fresh fruity accords and in flavours.
Typical role: modifier (used in small amounts to change the character of a blend).
How Hexyl Butyrate differs from similar materials
- Hexyl 2-Methylbutyrate
- The 2-methylbutyrate adds banana, unripe strawberry and a woody, spicy-tropical nuance; hexyl butyrate is plainer green apple and wax.
- cis-3-Hexenyl Butyrate
- The cis-3-hexenyl ester is greener and buttery-brandy; hexyl butyrate is a waxy, soapy green apple.
Each difference compares the published descriptions of the two materials. Smell varies with grade, supplier and dilution; compare them side by side on blotters before substituting one for another.
Identity and classification
- Type
- Aroma chemical
- Origin
- Occurs in nature
- Odour family
- Fruity / Green
- Note position
- Top note
- Physical form at room temperature
- Liquid
- Also known as
- Hexyl butanoate
- CAS number
- 2639-63-6
- Molecular formula
- C10H20O2
- Molecular weight
- 172.26 g/mol
- IUPAC name
- hexyl butanoate
The CAS number, formula and molecular weight are taken from PubChem compound 17525, whose own record lists this CAS number; checked 19 October 2026.
Safety and compliance
Hazard classification of the neat substance, as PubChem summarises it, read 26 October 2026. Companies notifying the ECHA C&L Inventory report it as not meeting the GHS hazard criteria (1,650 of 1,679 reports). Unless it is harmonised, this is the notifiers' own classification, not a binding one.
This page is general information, not a safety assessment or a specification. Confirm identity, composition, IFRA status and allergen content from your supplier's documents for the lot you hold.
Materials it works with
Hexyl Butyrate is also suggested as a partner on the pages for cis-3-Hexenyl Butyrate.
Used in formulas and accords
Used in 1 published formula
Hexyl Butyrate is an ingredient in 1 perfume formula in the Formula & Accord Library.
RUŌOD House Originals
Original compositions by RUŌOD House.
Further reading
Questions about Hexyl Butyrate
Is Hexyl Butyrate natural or synthetic?
The molecule occurs in nature. Commercial Hexyl Butyrate may be made by synthesis or obtained from natural sources, so check the supplier's specification if the distinction matters to you.
What is the CAS number of Hexyl Butyrate?
2639-63-6. It was checked against PubChem on 19 October 2026.
Which published formulas use Hexyl Butyrate?
Hexyl Butyrate is used in 1 published formula in the RUŌOD Lab Formula & Accord Library: Apple Cellar. Each is listed with a link under "Used in formulas and accords" on this page.
Sources
- PubChem — compound 17525, checked 19 October 2026.
- PubChem — GHS classification (the ECHA C&L Inventory notifications and any harmonised EU entry), read 26 October 2026.
- The Good Scents Company — hexyl butyrate (Mosciano and supplier descriptions) — odour database.
- Perflavory — hexyl butyrate — odour database.
- Olfactory profile: the RUŌOD Lab team's synthesis of the published descriptions above, reviewed 20 October 2026. Evidence: more than one published description. Classification and the short description: revision 1. Descriptions of odour are judgement, not measurement.








