Hexyl Butyrate

Aroma chemical · Fruity / Green

fruity, green apple, fresh, waxy — top note.

Aroma illustration for Hexyl Butyrate: green apples and a wax candle, for its green apple and waxy notes. It illustrates smell associations, not the material or its source.Skeletal formula of Hexyl Butyrate (Hexyl butanoate), C10H20O2, drawn from PubChem's 2D record. Stereochemistry is not shown.
Aroma View: an illustration of what Hexyl Butyrate smells like (green apple, waxy), drawn by RUŌOD Lab — not its appearance or its source.Skeletal formula drawn by RUŌOD Lab from PubChem's 2D record (CID 17525). Stereochemistry is not shown; the coloured background is decoration.
Images

By the RUŌOD Lab TeamRevision 1Updated

In short

Hexyl butyrate is a fruity ester with a fresh green-apple odour. It occurs in apples and other fruit and is used for crisp, natural apple effects.

What Hexyl Butyrate smells like

Hexyl butyrate is a green, fruity ester with an apple character and a waxy, slightly soapy skin. Supplier data list green, sweet, fruity, apple, waxy and soapy; a perfumery entry green, fruity, estery and vegetative with a waxy undertone; Blue Marble's natural grade green, fruity, sweet, soapy and waxy, apple-like. Its taste is green, fruity, waxy and soapy.

Leading note
Green apple
Clear facets
Waxy skin
Supporting facets
Soapy
Faint facets
Vegetative
Character
Green, waxy, fresh
  • fruity
  • green apple
  • fresh
  • waxy

What makes Hexyl Butyrate distinctive

Apple skin rather than apple flesh: green and waxy, with a faint soapiness.

How Hexyl Butyrate is used

Used in green-apple and fresh fruity accords and in flavours.

Typical role: modifier (used in small amounts to change the character of a blend).

How Hexyl Butyrate differs from similar materials

Hexyl 2-Methylbutyrate
The 2-methylbutyrate adds banana, unripe strawberry and a woody, spicy-tropical nuance; hexyl butyrate is plainer green apple and wax.
cis-3-Hexenyl Butyrate
The cis-3-hexenyl ester is greener and buttery-brandy; hexyl butyrate is a waxy, soapy green apple.

Each difference compares the published descriptions of the two materials. Smell varies with grade, supplier and dilution; compare them side by side on blotters before substituting one for another.

Identity and classification

Type
Aroma chemical
Origin
Occurs in nature
Odour family
Fruity / Green
Note position
Top note
Physical form at room temperature
Liquid
Also known as
Hexyl butanoate
CAS number
2639-63-6
Molecular formula
C10H20O2
Molecular weight
172.26 g/mol
IUPAC name
hexyl butanoate

The CAS number, formula and molecular weight are taken from PubChem compound 17525, whose own record lists this CAS number; checked 19 October 2026.

Safety and compliance

Hazard classification of the neat substance, as PubChem summarises it, read 26 October 2026. Companies notifying the ECHA C&L Inventory report it as not meeting the GHS hazard criteria (1,650 of 1,679 reports). Unless it is harmonised, this is the notifiers' own classification, not a binding one.

This page is general information, not a safety assessment or a specification. Confirm identity, composition, IFRA status and allergen content from your supplier's documents for the lot you hold.

Materials it works with

Hexyl Butyrate is also suggested as a partner on the pages for cis-3-Hexenyl Butyrate.

Used in formulas and accords

Used in 1 published formula

Hexyl Butyrate is an ingredient in 1 perfume formula in the Formula & Accord Library.

RUŌOD House Originals

Original compositions by RUŌOD House.

Further reading

Questions about Hexyl Butyrate

Is Hexyl Butyrate natural or synthetic?

The molecule occurs in nature. Commercial Hexyl Butyrate may be made by synthesis or obtained from natural sources, so check the supplier's specification if the distinction matters to you.

What is the CAS number of Hexyl Butyrate?

2639-63-6. It was checked against PubChem on 19 October 2026.

Which published formulas use Hexyl Butyrate?

Hexyl Butyrate is used in 1 published formula in the RUŌOD Lab Formula & Accord Library: Apple Cellar. Each is listed with a link under "Used in formulas and accords" on this page.

Sources

Your own records, next to the reference

Keep your own record of Hexyl Butyrate — supplier, cost, stock, dilutions and where it is used — in RUŌOD Lab's material library.