1-Hexanol

Aroma chemical · Green / Fruity

green, sweet, fruity, mild — top note.

Aroma illustration for 1-Hexanol: green leaves and bright abstract fruit-coloured spheres, for its green and fruity notes. It illustrates smell associations, not the material or its source.Skeletal formula of 1-Hexanol (Alcohol C-6), C6H14O, drawn from PubChem's 2D record. Stereochemistry is not shown.
Aroma View: an illustration of what 1-Hexanol smells like (green, fruity), drawn by RUŌOD Lab — not its appearance or its source.Skeletal formula drawn by RUŌOD Lab from PubChem's 2D record (CID 8103). Stereochemistry is not shown; the coloured background is decoration.
Images

By the RUŌOD Lab TeamRevision 1Updated

In short

1-Hexanol (alcohol C-6) is the saturated relative of leaf alcohol, found in fruits and leaves. JECFA describes a mild, sweet, green odour.

What 1-Hexanol smells like

JECFA, as published by PubChem, describes 1-hexanol as a colourless, mobile liquid with a mild, sweet, green odour; HSDB calls it a sweet, pleasant alcohol and Haz-Map a colourless liquid with a fruity odour. PubChem links it to several natural-product databases.

Leading note
Mild green
Supporting facets
Sweet, fruity
Character
Soft
  • green
  • sweet
  • fruity
  • mild

What makes 1-Hexanol distinctive

The softer, saturated cousin of leaf alcohol.

How 1-Hexanol is used

A flavouring that JECFA has evaluated, and one PubChem links to several natural-product databases. In perfumery it gives a mild, sweet, green-fruity freshness in small amounts, in green and fruity top notes.

Typical role: modifier (used in small amounts to change the character of a blend).

How 1-Hexanol differs from similar materials

cis-3-Hexenol
Leaf alcohol is the sharp, freshly cut grass note; 1-hexanol, without its double bond, is milder, sweet and green.

Each difference compares the published descriptions of the two materials. Smell varies with grade, supplier and dilution; compare them side by side on blotters before substituting one for another.

Identity and classification

Type
Aroma chemical
Origin
Occurs in nature
Odour family
Green / Fruity
Note position
Top note
Physical form at room temperature
Liquid
Also known as
Alcohol C-6, Hexyl alcohol
CAS number
111-27-3
Molecular formula
C6H14O
Molecular weight
102.17 g/mol
IUPAC name
hexan-1-ol

The CAS number, formula and molecular weight are taken from PubChem compound 8103, whose own record lists this CAS number; checked 24 October 2026.

Safety and compliance

Hazard classification of the neat substance, as PubChem summarises it, read 26 October 2026. It has a harmonised EU classification (Regulation (EC) No 1272/2008, Annex VI): H302 harmful if swallowed. Companies notifying the ECHA C&L Inventory classify it (2,711 reports): H319 causes serious eye irritation (35.5% of reports); H226 flammable liquid and vapor (34.3% of reports); H312 harmful in contact with skin (33.5% of reports); H302+H312 harmful if swallowed or in contact with skin (23.3% of reports). Unless it is harmonised, this is the notifiers' own classification, not a binding one.

This page is general information, not a safety assessment or a specification. Confirm identity, composition, IFRA status and allergen content from your supplier's documents for the lot you hold.

Materials it works with

Used in formulas and accords

Used in 1 published formula

1-Hexanol is an ingredient in 1 perfume formula in the Formula & Accord Library.

RUŌOD House Originals

Original compositions by RUŌOD House.

Further reading

Questions about 1-Hexanol

Is 1-Hexanol natural or synthetic?

The molecule occurs in nature. Commercial 1-Hexanol may be made by synthesis or obtained from natural sources, so check the supplier's specification if the distinction matters to you.

What is the CAS number of 1-Hexanol?

111-27-3. It was checked against PubChem on 24 October 2026.

Which published formulas use 1-Hexanol?

1-Hexanol is used in 1 published formula in the RUŌOD Lab Formula & Accord Library: Cut Stem Atelier. Each is listed with a link under "Used in formulas and accords" on this page.

Sources

  • PubChem — compound 8103, checked 24 October 2026.
  • PubChem — GHS classification (the ECHA C&L Inventory notifications and any harmonised EU entry), read 26 October 2026.
  • PubChem — 1-Hexanol (CID 8103): JECFA organoleptic description — odour database.
  • Olfactory profile: the RUŌOD Lab team's synthesis of the published descriptions above, reviewed 26 October 2026. Evidence: more than one published description. Classification and the short description: revision 1. Descriptions of odour are judgement, not measurement.

Your own records, next to the reference

Keep your own record of 1-Hexanol — supplier, cost, stock, dilutions and where it is used — in RUŌOD Lab's material library.